Production and application of isostatically pressed refractory materials

introduction of Isostatical refractory

Definition of the three isostatical refractory

the monolithic stopper rod, the ladle shroud, and the submerged entry nozzle—are essential refractory materials used in continuous steel casting. They primarily serve to protect the casting process (ladle shroud and submerged entry nozzle) and control the flow of molten steel (stopper rod).

ladle shroud-sub entry nozzle-tundish stopper rod-tundish nozzle
ladle shroud-sub entry nozzle-tundish stopper rod-tundish nozzle

Here is the table that explain the function of ladle shroud,tundish stopper,sub entry shroud,and ladle shroud manipulator

ComponentPrimary Function
Submerged NozzleControls molten steel flow to prevent contamination and maintain consistent temperature.
Tundish ShroudManages the flow between ladle and tundish, ensuring a steady steel supply while reducing splashes and air exposure.
Tundish StopperRegulates molten steel flow rate, providing control during the continuous casting process.
Ladle ShroudProtects molten steel from oxidation during transfer from ladle to tundish, improving steel purity.
Ladle Shroud ManipulatorAllows for accurate and safe placement of ladle shrouds, ensuring optimal molten steel transfer and increasing operator safety in the continuous casting process.

Classification of stoppers:

  1. Based on additional functions, they can be classified as:

a: Standard stopper

b: Ventilated stopper

tundish stopper rod
tundish stopper rod

2. Classification by connection method:

a: Threaded type

b: Pin-type

tundish stopper rod structure
tundish stopper rod structure

Classification of submerged tundish nozzles

  • Submerged tundish nozzles for square and round billets
  • Submerged tundish nozzles for medium-thick slabs
  • Submerged tundish nozzles for thin slabs
sub entry nozzle
sub entry nozzle
the structure of sub entry nozzle
the structure of sub entry nozzle

Types of ladle shroud:

  • Standard ladle shroud
  • Argon-shielded ladle shroud
ladle shroud
ladle shroud
the strcture of the ladle shroud
the strcture of the ladle shroud

the design and production of isostatical refractory

Stopper Rod Body Design:

the tundish stopper rod design
the tundish stopper rod design

The rod body design takes into account safety and installation factors. The overall wall thickness of the rod must be greater than 40mm, and at the slag line, it must be no less than 50mm. If a carbon fiber plug is used, the wall thickness at the plug location must be no less than 30mm.

The design of sections A and B of the rod tail: The rod tail consists of two sections. Section A is a straight section, which ensures high strength near the plug. Section B is a tapered section, which ensures the required slag line thickness.

Additionally, the inner core diameter must be controlled. Increasing the inner core diameter can reduce rod bending and core deformation, but it also reduces the rod wall thickness.

Stopper Head Design:

the design of tundish stopper rod
the design of tundish stopper rod

Common types of stopper head include:

1. Semi-circular tip;

2. Three-segment arc tip;

3. Two-segment arc tip;

4. Two-arc with diagonal line tip.

The taper of these four types of plug tips gradually decreases from left to right. A larger taper results in longer lifespan and stronger wear resistance, but poorer flow control accuracy. This type of head is suitable for slab casting with high flow rates and severe wear. Conversely, a smaller taper results in shorter lifespan and weaker wear resistance, but better flow control accuracy. This type of plug is suitable for billet casting with lower flow rates and less slag carryover. Currently, the most commonly used plug tip is the three-segment arc type. This type offers good wear resistance and high flow control accuracy, and its taper can be adjusted by varying the radius of the three arcs to suit most continuous casting applications.

Relationship between the stopper rod and the tundish nozzle

Relationship between the stopper rod and the tundish nozzle
Relationship between the stopper rod and the tundish nozzle

The effective stroke of the stopper rod is related to the shape and dimensions of the stopper rod and the tundish nozzle as follows:

the data

 the data

Where:

Y…Effective stroke of the stopper rod;

Rn…Radius of the tundish nozzle;

x…Contact angle between the stoper rod and the tundish nozzle;

y…Radius of the contact circumference between the stopper rod and the tundish nozzle.

Sub Entry Nozzle  Design

sub entry nozzle design
sub entry nozzle design

Figure A shows a conical design, while Figure B shows a combination of a cylindrical and conical shape.

In the figures:

φA – Outer diameter of the top surface of the conical or cylindrical sprue;

φB – Opening diameter of the sprue bowl;

φC – Diameter at the point where the arc of the sprue bowl is tangent to the flow channel of the molten metal; this line is called the throat line;

φD – Outer diameter of the bottom end of the conical sprue;

R – Radius of the arc of the sprue bowl;

h – Height of the conical section;

h1 – Depth of the throat line;

h2 – Height of the cylindrical section of the sprue bowl;

h – Total height of the cylindrical and conical sections of the sprue.

SEN Rear design:

sub entry nozzle design

Common mold dimensions used in steel mills:

1. Continuous casting molds for small square billets: 120mm–150mm;

2. Continuous casting molds for large square billets and rectangular billets: 160–380mm;

3. Continuous casting molds for round billets: φ150mm–φ310mm;

4. Continuous casting molds for slabs: narrow side dimension between 140mm and 300mm.

Design specifications:

Outer diameter of the tundish nozzle = [mold narrow side dimension] – 2 × (30–40mm);

Wall thickness of the tundish nozzle = [outer diameter of tundish nozzle – diameter of molten steel flow channel] ÷ 2;

Side-entry hole design and slag line design

the lower part of sub entry nozzle
the lower part of sub entry nozzle

Empirical Dimensions for Side-Port Steel Pouring:

The total cross-sectional area of ​​the two side ports should be slightly larger than or equal to twice the cross-sectional area of ​​the central pouring channel. This ensures a stable steel flow and slow expansion rate.

Side Port Inclination Angle:

The inclination angle of the side ports can be horizontal, upward, or downward, typically ranging from 15° to 30°. Currently, a 15° downward inclination is more common. The thickness of the bottom of the side port is generally controlled between 25 and 40 mm.

Slag Line:

Due to the vibration frequency and amplitude of the mold, this area is subjected to alternating erosion by the protective slag and molten steel, forming a crescent-shaped groove with a width of 50–60 mm. The thickness (b) of the slag line layer is generally between 8 and 15 mm, and its height (h) is calculated as follows: Slag line height h = 3 × (50–60 mm)

Ladle shroud Bowl rim design

the bowl part of ladle shroud
the bowl part of ladle shroud

Classification of bowl lip designs:

  1. Step-type lip: Advantages: Compared to a conical lip, it reduces pressure on the lip and facilitates removal of the slag.
  2. Conical lip.

Dimensioning:

For a step-type lip, the dimension C (step height) should be determined based on the thickness of the ladle nozzle wall, ensuring that the inner diameter of the nozzle is greater than the mating depth H (generally 45–70 mm). The sealing area between the nozzle and the lip is located on the step, and the taper angle of the inclined edge should be determined based on the taper angle of the ladle nozzle. 

Designed to work in conjunction with the lower nozzle.

ladle shroud design with the collector nozzle
the ladle shroud design with collector nozzle

1. When the bottom of the bowl part is in contact with the platform, there should be a gap of approximately 1mm between the side wall of the cup and the bottom of the ladle outlet.

2. The taper of the bowl part should be greater than that of the ladle outlet, i.e., with an outward inclination of 1-2°.

3. If a 3mm fiber pad is used, the distance between the upper edge of the bowl and the ladle lower should be 2-3mm. If a 5mm fiber pad is used, increase the gap by 0.5mm.

Design principles for a conical pouring cup:

 

Similar to the flat-bottomed design, the engagement depth should be between 45-70mm, and the distance between the upper edge of the cup and the ladle outlet should be 2-3mm. This design allows for a slight reduction in the actual engagement depth when a fiber pad is used.

Ladle shroud dimention design

ladle shroud dimention
ladle shroud dimention
  1. The distance between the bottom of the ladle and the liquid level in the tundish;
  2. Whether the ladle can be lifted, and whether changing the tundish nozzle is convenient;
  3. Ensure that the bottom of the tundish nozzle is at least 350mm above the bottom of the tundish, with the immersion depth in the liquid level being between 150 and 300mm.

Diameter and Thickness Design:

The diameter is designed based on the molten steel flow rate and the shape of the tundish nozzle. The minimum inner diameter of the tundish nozzle should be at least 10mm larger than the minimum diameter of the ladle outlet to ensure smooth flow of molten steel and prevent spillage. The wall thickness of the tundish nozzle is generally between 25 and 35mm.

The design concept for raw materials

The design concept for raw materials of iso refractory
The design concept for raw materials of iso refractory

Production process

Production process of iso refractory
Production process of iso refractory

mixing

the mixing of iso refractory
the mixing of iso refractory

particling

ØFor dry-pressing of ceramic materials, the powder must have good flowability, high bulk density, and minimal or no fine particles; furthermore, the amount of binder used must be precisely controlled.

ØThere are currently three commonly used methods for granulating dry powder feedstock: conventional granulation, pressure granulation, and spray granulation.

ØIn production, it is generally necessary to control the particle size, moisture content, and plasticity of the granules.

forming

the forming of iso refractory
the forming of iso refractory

Drying

ladle shroud,sub entry nozzle,stopper rod drying

Burning

the burning of iso refractory

Inspection-process-spraying

1.Nondestructive testing uses the penetrating power of X-rays to detect internal defects such as impurities, pores, segregation, and cracks in a product, without damaging the product itself. 

2.The machining processes mainly include:

  1. Turning external surfaces
  2. Cutting edges
  3. Milling holes
  4. Machining sleeves
  5. Grinding surfaces

3.Two layers of coating, with a combined thickness not exceeding 1mm, are sprayed onto the product surface. The purpose of this coating is to form a glassy glaze layer during baking, which acts as a barrier to oxygen, preventing oxidation of the product.

the production process of iso refractory
the production process of iso refractory

the installation and application of isostatical refractory

Stopper installation

tundish stopper manipulator
tundish stopper manipulator

Installation process

 

Installation process of tundish stopper manipulator

1.      Insert the rod with the threaded shaft attached into the central sleeve.

2.      Attach the sealing rod to the mechanism.

3.      adjust the stopper

Notes

1、 The mechanism should be designed to ensure good performance; it should be thoroughly tested and adjusted to guarantee sufficient lubrication.

2、 During installation, pay attention to ensuring proper alignment with the tundish nozzle position. ;

3、 Prevent any debris from accumulating between the stopper rod and the tundish nozle, as this could cause molten steel to leak out and result in a failed casting process.

4、 Be careful to protect the plug pin; do not hit it directly. When adjusting the switch, use appropriate force; avoid damaging the protective coating on the surface.

ladle shroud installation
ladle shroud installation

Sub entry nozzle installation

Installation of built-in, submersible water outlets of sub entry nozzle
Installation of built-in, submersible water outlets of sub entry nozzle

the common problem of isostatical refractory

broken rod

broken stopper rod
broken stopper rod

1、 Fractures during installation or baking are mainly caused by impacts that occur during the installation and adjustment process. 。

2、 The stopper rod fractured at the slag line, primarily due to the poor wear resistance of the material at that point; therefore, the material composition of the slag line area of ​​the stopper rod should be adjusted.

3、 Some steel mills intentionally offset the center line of the stopper rod by 5-10mm from the center line of the tundish nozzle during installation, to improve the operator’s control during operation. However, this can easily cause the rod tip to collide with the nozzle opening during operation, resulting in the stopper rod breaking.

4、 It is also important to be vigilant against sabotage by competitors on site, such as pouring water into the hole of the sealing rod.

Stopper Head drop

tundish stopper head drop

1、 Thermal shock (problems related to baking process and materials)

2、 Strength (excessive defects)

3、 External forces (sticking during baking, mechanical impact)

4、 Oxygen combustion (top-blown)

tundish stopper head adhesion

tundish stopper head adhesion
tundish stopper head adhesion

Stopper Rod head erosion

Stopper Rod head erosion
Stopper Rod head erosion

1.shape

2.special steel

3.agroning

4.Oxygen content (after combustion) 

Ladle shroud problem

  • Thermal shock damage
  • Slab erosion
  • Internal hole enlargement
  • Cracking and perforation
Thermal shock damage of ladle shroud
Thermal shock damage of ladle shroud
slagline erosion of ladle shroud
slagline erosion of ladle shroud
Internal hole enlargement of ladle shroud
Internal hole enlargement of ladle shroud
Cracking and perforation of ladle shroud
Cracking and perforation of ladle shroud

Sub Entry Nozzle problem

  • Perforation at the transition point
  • Perforation due to slag erosion
  • Enlargement of internal and side holes
  • Formation of clogging inside the mold cavity; blockage of the pouring gate
perforation at the transition point of sub entry nozzle
Perforation at the transition point of SEN
the leakage of sub entry nozzle
Perforation due to slag erosion of SEN
Enlargement of internal and side holes of sub entry nozzle
the leakage of sub entry nozle
clogging of sub entry nozzle
clogging of sub entry nozzle

The main reason for clogging in submerged nozzles is the reaction between oxygen in the refractory material and aluminum in the molten steel, which produces high-melting-point aluminum oxide. This aluminum oxide, along with any pre-existing aluminum oxide in the refractory material, tends to accumulate at the nozzle outlet, thus causing blockage.

ISO refractory Performance evaluation

Ø. Thermal shock resistance

Ø. Resistance to slag erosion

Ø. Abrasion resistance

Ø. Overall service life

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